Highly Axial Magnetic Anisotropy in a N3 O5 Dysprosium(III) Coordination Environment Generated by a Merocyanine Ligand.
نویسندگان
چکیده
A spiropyran-based switchable ligand isomerizes upon reaction with lanthanide(III) precursors to generate complexes with an unusual N3 O5 coordination sphere. The air-stable dysprosium(III) complex shows a hysteresis loop at 2 K and a very strong axial magnetic anisotropy generated by the merocyanine phenolate donor.
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ورودعنوان ژورنال:
- Chemistry
دوره 22 43 شماره
صفحات -
تاریخ انتشار 2016